千葉大学 大学院工学研究科・工学部


05.11.14同仁化学において07.jpg
島津 省吾
シマヅ ショウゴ
Shogo Shimazu
資源プロセス化学領域
触媒化学研究室
教授
共生応用化学専攻
共生応用化学コース
共生応用化学科
043-290-3379
shimazu@
(@マーク以下にfaculty.chiba-u.jpと入力してください。)
http://chem.tf.chiba-u.jp/~shimazu/research/
京都工芸繊維大学繊維学部繊維化学科1978大阪大学大学院理学研究科1980 理学修士Texas A&M大学大学院理学研究科1983 Ph.D.
住友電気工業株式会社,千葉大学工学部助手,同大学院自然科学研究科助手,同工学部講師,同助教授, 2005年現職
日本化学会,触媒学会,日本イオン交換学会,高分子学会,米国化学会
触媒化学,錯体化学
無機層状化合物と遷移金属錯体を組合わせて新規ナノ構造体を創製し,従来の均一系錯体触媒を超えるファインケミカルズ合成に重要な分子認識触媒の開発を行っている. [1]不斉ホスフィン錯体の無機化合物層間固定化と不斉水素化触媒反応. [2]ピラー錯体を用いた無機-有機ナノ複合体の創製と高選択的触媒開発. [3]メソ多孔体表面固定化錯体を用いた分子認識触媒の開発. [4]固体触媒によるバイオマス変換反応プロセスの開発. [5]バイメタリクなナノ合金触媒を用いた不飽和ケトン類の官能基選択的触媒反応.
・Anionic D-Valine-Palladium(II) Complex Supported on Hydroxy Double Salt with Brønsted Basic Phosphate Anion: Application for Heterogeneous Catalyst toward Aerobic Alcohol Oxidation, Catalysis Science & Technology, in press (2011).
・Characterization of heat-treated synthetic imogolite by 27Al MAS and 27Al MQMAS solid state NMR, Bull. Chem. Soc. Jpn., 84, 656−659 (2011).
・Highly Efficient Pd/SiO2-Dimethyl Sulfoxide Catalyst System for Selective Semihydrogenation of Alkynes, Chem. Lett., 405−407 (2011).
・Hemicellulose Decomposition and Saccharides Production from Various Plant Biomass by Sulfonated Allophane Catalyst, Catal. Today, 164(1), 415-418 (2011).
・Fine Tuning of Pd0 Nanoparticle Formation on Hydroxyapatite and Its Application for Regioselective Quinoline Hydrogenation, Chem. Lett., 39(8), 832-834 (2010).
・Size Control of Catalytic Reaction Space by Intercalation of Alkylcarboxylate Anions into Ni-Zn Mixed Basic Salt Interlayer: Application for Knoevenagel Reaction in Water, Chem. Lett., 39(3), 304-305 (2010).
・Complete Hydrodechlorination of DDT and Its Derivatives Using a Hydroxyapatite-supported Pd Nanoparticle Catalyst, Chem. Lett., 39(1), 49-51(2010).
・Nb and Fe K-edges XAFS study on the structure of supported Fe-NbN catalysts, Journal of Physics: Conference Series, 190, 1-4(2009).
・Selective Production of Xylose and Xylo-oligosaccharides from Bamboo Biomass by Sulfonated Allophane Solid Acid Catalyst, Chem. Lett., 38, 1176-77(2009).
・Creation of Highly Stable Monomeric Pd(II) Species in an Anion-Exchangeable Hydroxy Double Salt Interlayer: Application to Aerobic Alcohol Oxidation under an Air Atmosphere, Green Chem., 11, 2034 – 2040(2009).
・Characterization of CuMn-spinel catalyst for methanol steam reforming, Catalysis Commun., 10, 1800-3 (2009).
・Promoting Effect of Iron for the Nitriding Process of Niobium Oxide into NbN Catalysts, Topics in Catalysis, 52(11), 1517-1524 (2009).
・The influence of metals and acidic oxide species on the steam reforming of dimethyl ether (DME), Applied Catalysis A: General, 348, 193-200 (2008).
・Preparation of supported NbC catalysts from peroxoniobic acid and in situ XAFS characterization, Applied Catalysis A: General, 343, 25-28 (2008).
・Highly Efficient Alcohol Oxidation Catalyzed by Palladium(II)-alkylamine Complexes Using Atmospheric Molecular Oxygen: Journal of Molecular Catalysis A: Chem., 282, 28-33(2008).
・Regioselective Ring Opening Reactions of Oxiranes with Acrylic Acid by Clay Supported Zirconium β-diketonate Catalysts, Journal of Ion Exchange, 18(4), 548-589 (2007).
・Effect of Co addition for carburizing process of Ti-oxide/SiO2 into TiC/SiO2, Applied Catalysis, A: General, 323, 104-109 (2007).
・XAFS study of the photo-active site of Mo/MCM-41, AIP Conference Proceedings, 882 (X-Ray Absorption Fine Structure (XAFS13)), 672-674 (2007).
・In-situ XAFS characterization for nitriding process of silica supported Nb catalysts under N2-H2 gas, AIP Conference Proceedings, 882 (X-Ray Absorption Fine Structure (XAFS13)), 639-641 (2007).
・無機イオン交換体を利用したナノ構造体触媒の創製, 日本イオン交換学会誌, 18(2), 60-67(2007).
・Amino acid adsorption onto mesoporous silica molecular sieves, Separation and Purification Technology, 48, 197–201 (2006).
・Studies on tris(β-diketonato)zirconium(IV); syntheses, characterization and catalytic activity for regio-selective ring opening of oxiranes, Catal. Commun., 6, 426-430(2005).
・Selective Synthesis of Primary Methoxypropanol Using Clay Supported Tris(2,4-pentadionato)zirconium(IV), J. Mol. Catal. A: Chem., 221(1-2), 141-144(2004).
・Synthesis of nano-structured clays: unique conformation of pillar complexes, Chem. Lett., 33(3), 208-209(2004).
・Asymmetric Hydrogenation of Acetophenone by Rh(I)-BINAP Supported on Smectites with Various Interlayer Distances, J. Ion Exch., 14, 397-400 (2003).
・Regioselective hydrogenation of dienes catalyzed by palladium-aminosilane complexes grafted on MCM-41, J. Mol. Catal. A: Chem., 182-183, 343-350 (2002).
・Catalytic Hydrogenation in Aqueous Media by Metal Complexes Supported on Inorganic Layer Compounds, Indonesian Journal on Environmental Chemistry and Toxicology, 1, 19-23 (2002).
・Asymmetric Hydrogenation of α,β-Unsaturated Carboxylic Acid Esters by Rh(I) Phosphine Complexes Supported on Smectites, J. Mol. Catal. A, 107, 297(1996).
・触媒調製ハンドブック, 1章Pd/粘土鉱物層間固定化触媒, NTS, 2011年, pp.32-33, 文筆.
・図解 最先端イオン交換技術のすべて,3章3−15触媒, 工業調査,2009年, 共著
・物理化学, 6, 7章, みみずく舎, 2008年, 共著.
・無機材料必須300−原理・物性・応用−, 守吉佑介他編, 三共出版, 2008, pp. 236-239, 文筆.
・分子認識化学, 三共出版, 1997, 共著.
・物理化学, 朝倉, 1996, 共著
物理DI(学部1年)、錯体化学(学部3年)、大学院物理化学(院)、資源物理化学(院)、バイオ触媒化学特論(院)
研究概要 Shimazu 08.08.27 B.pdf(08.27 B.pdf)